I. Ionisation potential (or Ionization energy) is the energy required to remove an electron from an atom. It generally increases along a period (from left to right) due to increasing nuclear charge and decreasing atomic size, making it harder to remove an electron. Statement I is false. II. Electron affinity is the energy change when an electron is added to a neutral atom to form a negative ion. In a group, as atomic weight (and atomic number/size) increases down the group, the nucleus's attraction for an incoming electron decreases due to increased distance and shielding effect. Thus, electron affinity generally decreases down a group. Statement II is correct. III. Electronegativity is the measure of an atom's ability to attract electrons in a chemical bond. In a given period, electronegativity generally increases as the atomic number increases (from left to right) due to increasing nuclear charge and decreasing atomic size. Statement III is false.
Consider the following statements with reference to the Periodic Table of chemical elements: I. lionisation potential gradually decreases along a period. II. In a group of elements, electron affinity decreases as the atomic weight increases. III. In a given period, electronegativity decreases as the atomic number increases. Which of these statement(s) is/are correct?
Asked in UPPCS Prelims 2001 · Topic: Inorganic Chemistry (Atomic Structure and Periodicity)
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