- The thermite reaction involves the reduction of a metal oxide by a more reactive metal, producing a large amount of heat and molten metal. - The specific reaction used for rail welding is between iron(III) oxide (Fe₂O₃) and aluminium (Al): 2Al + Fe₂O₃ → Al₂O₃ + 2Fe + Heat. - The molten iron produced at high temperature fills the gap between the rails, creating a weld.