The formation of photochemical smog is driven by sunlight. Nitrogen dioxide (NO₂) is a primary pollutant that photodissociates in sunlight to form nitric oxide (NO) and atomic oxygen (O). This atomic oxygen quickly reacts with molecular oxygen (O₂) to form ozone (O₃). VOCs react with NOx and other atmospheric components in the presence of sunlight to form a variety of secondary pollutants, including PAN. Therefore, NO₂, O₃ (as a product), and PAN (as a product), with sunlight as the driving force, are central to photochemical smog.