Calcium is a relatively reactive metal that reacts with acids like sulfuric acid to produce hydrogen gas and a salt: Ca(s) + H₂SO₄(aq) → CaSO₄(s) + H₂(g). However, calcium sulfate (CaSO₄) is sparingly soluble in water, and its solubility is even lower in concentrated sulfuric acid. As the reaction proceeds, a layer of solid calcium sulfate forms on the surface of the calcium metal. This layer acts as a barrier, preventing the sulfuric acid from coming into contact with the underlying calcium metal, effectively stopping or significantly slowing down the reaction after a short while. This phenomenon is known as passivation.
When calcium metal reacts with sulphuric acid, the reaction stops after a short while. Why?
Asked in UPSC CAPF 2021 · Topic: Metals, Minerals, Ores: Properties, Uses (Chemical properties of metals (reaction with oxygen, water, acids, bases, other metal salts))
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Answer: B. Formed calcium sulphate is insoluble in water and covers the metal, preventing it from reacting any further
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