The stability of an electronic configuration increases significantly when subshells are completely filled or half-filled. For f-orbitals, a half-filled configuration means having 7 electrons ($f^7$). - Europium (Eu, Z=63) has the electronic configuration $ [Xe] 4f^7 6s^2 $. Its $4f$ subshell is half- filled. - Gadolinium (Gd, Z=64) has the electronic configuration $ [Xe] 4f^7 5d^1 6s^2 $. Its $4f$ subshell is half-filled. The other elements given do not have half-filled f-orbitals in their ground state: - Samarium (Sm, Z=62): $ [Xe] 4f^6 6s^2 $ - Terbium (Tb, Z=65): $ [Xe] 4f^8 5d^1 6s^2 $ - Promethium (Pm, Z=61): $ [Xe] 4f^5 6s^2 $ Thus, Eu and Gd are the elements with half-filled f-orbitals.
Which of the following elements have half- filled f-orbitals in their ground state? (Given: atomic number, Sm = 62, Eu = 63, Tb = 65, Gd = 64, Pm = 61) - (A) Sm - (B) Eu - (C) Tb - (D) Gd - (E) Pm Choose the correct answer from the options given below - - (5) Question not attempted
Asked in Department Recruitment 2024 (Chemist) 2024 · Topic: Atomic Structure (Atomic Orbitals (Shapes and energies of s, p, d, f orbitals, nodal surfaces))
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