- A double salt is a crystalline salt that contains two different cations or anions and crystallizes as a single structure. - When dissolved in water, a true double salt dissociates completely into simple ions. For K₂SO₄. Al₂(SO₄)₃. 24H₂O, it dissolves to give K⁺, Al³⁺, and SO₄²⁻ ions in solution. - Examples of double salts include alums (like potash alum), Mohr's salt (FeSO₄.(NH₄)₂SO₄.6H₂O), and carnallite (KCl.MgCl₂.6H₂O). - Option A (FeSO₄. 6H₂O) is a hydrated simple salt. - Option B (Pb(OH)NO₃) is a basic salt. - Option D (K₄ [Fe(CN)₆]) is a complex salt or coordination compound. In solution, it dissociates into K⁺ ions and the complex ion [Fe(CN)₆]⁴⁻, which does not break down into Fe²⁺ and CN⁻ ions, thus retaining its identity.